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10MbAbstractMultichannel Quantum Defect Theory (MQDT) is shown to be capable of producing quantitatively accurate results for low energy atom molecule scattering calculations. With a suitable choice of reference potential and short range matching distance, it is possible to dene a matrix that encapsulates the short range collision dynamics. Multichannel quantum defect theory can provide an ecient alternative to full coupled channel calculations for low energy molecular collisions. However, the eciency relies on interpolation of the Y matrix that encapsulates the short range dynamics. It is shown how the phases of the MQDT reference functions may be chosen so as to remove such poles from the vicinity of a reference energy and dramatically increase the range of interpolation. For the test cases of Mg+NH and Li+NH, the resulting optimized Y matrix may be interpolated smoothly over an energy range of several Kelvin and a magnetic eld range of over 1000G. Calculations at additional energies and elds can then be performed at a computational cost that is proportional to the number of channels N and not to N cubed. MQDT thus provides a promising method for carrying out low energy molecular scattering calculations on systems where full exploration of the energy and the eld dependence is currently impractical. .
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